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Porphyrins and PhthalocyaninesMaterials Research Group |
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Hexaphyrin-based anion chemosensors are reported for the first time. The meso-hexakis(ethylenediamine)-substituted [28]hexaphyrins 2 and 3 revealed strong affinity for F−, AcO− and H2PO4−. Adsorption constants in aqueous media were determined on a gold piezoelectric crystal coated with 2 and 3. 1H NMR titrations and molecular dynamics simulations showed the main interactions between hosts and guests. Chem. Commun., 2016, 52, 2181-2184.
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